Which of the following organic compounds is a benzenoid?

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SSC CPO 2024 Official Paper-I (Held On: 27 Jun, 2024 Shift 3)
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  1. Acetaldehyde
  2. Propane
  3. Hexane
  4. Aniline

Answer (Detailed Solution Below)

Option 4 : Aniline
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The correct answer is Aniline

Key Points

  • Aniline is a benzenoid compound, as it contains a benzene ring in its structure.
  • Benzenoid compounds are aromatic compounds that feature at least one benzene ring.
  • In contrast, acetaldehyde, propane, and hexane are not benzenoid compounds as they do not contain a benzene ring.
  • Aniline, with the chemical formula C6H5NH2, is an aromatic amine and a key starting material in the manufacture of dyes, drugs, and plastics.

Additional Information

  • Benzene is the simplest aromatic hydrocarbon and a precursor to many other aromatic compounds.
  • Organic compounds are classified as aromatic if they follow the Hückel’s rule, which states that the compound must have a planar ring of continuously overlapping p-orbitals and 4n+2 π-electrons.
  1. Aniline is synthesized industrially by the reduction of nitrobenzene or by the amination of chlorobenzene.
  • Due to its aromatic nature, aniline undergoes electrophilic substitution reactions, which are typical of benzene derivatives.
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