Which of the following properties changes with valency?

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RRB JE CBT I - (Held On: 30 May 2019 Shift 1)
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  1. Equivalent weight 
  2. Density
  3. Volume
  4. Pressure

Answer (Detailed Solution Below)

Option 1 : Equivalent weight 
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The correct answer is Equivalent weight

Key Points

  • Equivalent weight changes with valency as it is defined as the mass of one equivalent of a substance, which is dependent on the valency.
  • Valency affects the calculation of equivalent weight because it determines the number of moles of electrons or ions that a substance can donate or accept.
  • The equivalent weight is calculated using the formula: Equivalent weight = Molecular weight / Valency.
  • Other properties like density, volume, and pressure do not directly change with valency.

Additional Information

  • Valency is the combining power of an element, often defined as the number of hydrogen atoms that can combine with or displace one atom of the element to form a compound.
  • The concept of equivalent weight is particularly useful in the context of acid-base titrations and redox reactions.
  • For example, in a redox reaction, the equivalent weight of an oxidizing or reducing agent is the quantity that reacts with one mole of electrons.
  • In acid-base chemistry, the equivalent weight of an acid is the mass that supplies or reacts with one mole of hydrogen ions (H+), while for a base, it is the mass that reacts with one mole of hydroxide ions (OH-).
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