Iron which resembles Cobalt and Nickel in properties has been placed far away from these elements. This was one of the limitations of:

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  1. Mendeleev's periodic table
  2. Dobereiner's triads
  3. Modern periodic table
  4. Newlands' law of octaves

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Option 4 : Newlands' law of octaves
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The correct answer is Newlands' law of octaves.

Key Points

  • The56 elements that were then known were examined in 1864 by British scientist John Newlands.
  • According to the law of octaves, every eighth element possesses characteristics that are identical when the elements are ordered in ascending order of atomic mass.
  • Cobalt and nickel are isolated from iron, which shares many of its physical characteristics.
  • The Law of Octaves was no longer relevant with the discovery of noble gases.
  • Newland's Law of Octaves' limitations:
    • In Newland's periodic table, several elements fit into the same positions.
    • Nickel and cobalt, for instance, were put in the same slot.
    • Elements with dissimilar properties were grouped together.
    • For instance, several metals, such as cobalt, nickel, and platinum, were classed with halogens.
    • The octaves of Newland's law was only accurate for elements up to calcium.
    • It was impossible to fit elements with larger atomic masses within octaves.
    • The octave pattern could not accommodate the later found components.
    • As a result, there was no room for the discovery of new elements using this system of classifying elements.

Additional Information

  • Mendeleev's periodic table:
    • Mendeleev stated that "Element characteristics are a periodic function of their atomic weight" in his renowned periodic law.
  • Dobereiner's triads:
    • Johann Wolfgang Dobereiner discovered groups of elements having related properties and named them Dobereiner's triads.
  • Modern periodic table:
    • The elements are organized in the current periodic table in order of increasing atomic number.
    • The periodic table has groups and periods. 
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