Which of the following represents a homologous series?

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AAI Junior Assistant (Fire Service) Official Paper (Held On: 15 Nov, 2022 Shift 2)
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  1. HCHO, CH3CHO, CH3CH2CHO
  2. CH3OH, CH3CHO, CH3CH2CH2OH
  3. HCOOH, CH3CHO, CH3CH2CHO
  4. HCHO, CH3CHO, CH3COCH3

Answer (Detailed Solution Below)

Option 1 : HCHO, CH3CHO, CH3CH2CHO
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Detailed Solution

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The correct answer is Option 1.

Key Points

  • A homologous series is a group of organic compounds with the same functional group and similar chemical properties.
  • The compounds in a homologous series differ by a constant unit, typically a -CH2- group.
  • In option 1, HCHO (formaldehyde), CH3CHO (acetaldehyde), and CH3CH2CHO (propionaldehyde) all belong to the aldehyde group, which is characterized by the presence of the -CHO functional group.
  • These compounds show a gradual change in physical properties such as boiling point and solubility, but their chemical properties remain consistent.

Additional Information

  • Functional Group:
    • A functional group is a specific group of atoms within a molecule that is responsible for the characteristic chemical reactions of that molecule.
    • Examples include -OH in alcohols, -COOH in carboxylic acids, and -CHO in aldehydes.
  • Homologous Series Characteristics:
    • Members of a homologous series have a general formula, like CnH2n+1CHO for aldehydes.
    • They show a gradation in physical properties such as boiling and melting points.
    • They exhibit similar chemical properties due to the presence of the same functional group.
  • Examples of Homologous Series:
    • Alkanes (e.g., methane, ethane, propane)
    • Alkenes (e.g., ethene, propene, butene)
    • Carboxylic acids (e.g., formic acid, acetic acid, propionic acid)
  • Importance of Homologous Series:
    • Simplifies the study of organic chemistry by grouping similar compounds together.
    • Aids in predicting the properties and reactions of compounds within the same series.
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