Which of the following is isoelectronic?

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  1. CO2, NO2
  2. \(\mathrm{NO}_{2}^{-}, \mathrm{CO}_{2}\)
  3. CN-, CO
  4. SO2, CO2

Answer (Detailed Solution Below)

Option 3 : CN-, CO
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Detailed Solution

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CONCEPT:

Isoelectronic Species

  • Isoelectronic species are atoms, ions, or molecules that have the same number of electrons.
  • To determine if species are isoelectronic, count the total number of electrons in each species and compare them.

EXPLANATION:

  • Calculate the number of electrons in each species:
    • CO2: C (6 electrons) + 2 * O (8 electrons each) = 6 + 16 = 22 electrons
    • NO2: N (7 electrons) + 2 * O (8 electrons each) = 7 + 16 = 23 electrons
    • NO2-: N (7 electrons) + 2 * O (8 electrons each) + 1 extra electron = 7 + 16 + 1 = 24 electrons
    • CN-: C (6 electrons) + N (7 electrons) + 1 extra electron = 6 + 7 + 1 = 14 electrons
    • CO: C (6 electrons) + O (8 electrons) = 6 + 8 = 14 electrons
    • SO2: S (16 electrons) + 2 * O (8 electrons each) = 16 + 16 = 32 electrons
  • Identify the isoelectronic pairs:
    • CN- (14 electrons) and CO (14 electrons) are isoelectronic.

Therefore, the correct answer is Option 3: CN- and CO.

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