Which is the IUPAC group prefix of acyl halide compounds?

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SSC CHSL Exam 2023 Tier-I Official Paper (Held On: 04 Aug, 2023 Shift 1)
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  1. Alkoxycarbonyl 
  2. Carbamoyl
  3. Cyano
  4. Halocarbonyl

Answer (Detailed Solution Below)

Option 4 : Halocarbonyl
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The correct answer is Halocarbonyl.

Key Points

  • The IUPAC group prefix of acyl halide compounds is "Halocarbonyl."
  • Acyl halides are also known as acid halides, and they are compounds that contain a carbonyl group (C=O) and a halogen atom (F, Cl, Br, or I) attached to the same carbon atom.
  • Alkoxycarbonyl is a group prefix used for compounds that contain an ester functional group (RCOOR') attached to an alkyl or aryl group.
  • Carbamoyl is a group prefix used for compounds that contain a carbamate functional group (NH2COOR') attached to an alkyl or aryl group.
  • Cyano is a group prefix used for compounds that contain a nitrile functional group (CundefinedN) attached to an alkyl or aryl group.

Additional Information

Class of compounds Functional group structure IUPAC group prefix IUPAC group suffix Example
Ethers -R-O-R-  alkoxy-     -  Ethoxyethane
Carboxylic acid -COOH  carboxy  -oic acid  Butanoic acid
Carboxylate ions -COO-       -  -oate  Sodium butanoate
Esters -COOR  alkoxy carbonyl  -oate   Methyl propanoate
Acyl halides -COX  halo carbonyl  -oyl halide  Butanoyl chloride
Amines -NH2,>NH,>N-  amino-  -amine  Butan-2-mine
Amides -CONH2, -CONHR, -CONR2  -carbamyl  -amide  Butanamide
Nitro compounds  -NO2  nitro         -  1-Nitrobutane
Sulphonic acids  -SO3H  sulpho  sulphonic acid  Methylsulphonic acid
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