In the ccp packing, the number of lattice points per unit area in the planes is in the order

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CSIR-UGC (NET) Chemical Science: Held on (26 Nov 2020)
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  1. (100) > (110) > (111)
  2. (100) > (111) > (110)
  3. (111) > (100) > (110)
  4. (111) > (110) > (100)

Answer (Detailed Solution Below)

Option 3 : (111) > (100) > (110)
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Concept:

Cubic Close Paking: 

  • The cubic close packing (ccp) is the name given to a crystal structure. When we put atoms in the octahedral void, the packing is the of the form ABCABC, the packing is known as cubic close packing (ccp).  

Explanation:

  • In case of (100) plane, 5 lattice points are present in the area is a2. Thus, the area occupied by 1 lattice point is (a2/4)=0.20a2.
  • In case of (110) plane, 6 lattice points are present in the area is \(\sqrt 2 {a^2}\) Thus, the area occupied by 1 lattice point is \({{\sqrt 2 {a^2}} \over 6}\)=0.23a2. 
  • In case of (111) plane, 6 lattice points are present in the area \({{\sqrt 3 } \over 4} \times \sqrt 2 a \times \sqrt 2 a = {{\sqrt 3 } \over 2}{a^2}\). Thus, the area occupied by 1 lattice point is \({{\sqrt 3 } \over {12}}{a^2}\) = 0.14a2.
  • Thus, In the ccp packing, the number of lattice points per unit area in the planes is in the order (111) > (100) > (110).


F1 Vinanti Teaching 16.05.23 D1
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Conclusion:-

So, In the ccp packing, the number of lattice points per unit area in the planes is in the order (111) > (100) > (110)

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