Which of the property is shown by the cathode electrode during electrolysis?

  1. Oxidation occurs
  2. Reduction occurs
  3. Redox occurs
  4. None

Answer (Detailed Solution Below)

Option 2 : Reduction occurs
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Detailed Solution

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The correct answer is Reduction occurs.

Concept:

  • Electrolysis
    • Passing of direct electric current in the compound.
    • It decomposes ionic compounds into their elements.

 

Explanation:

  • At Cathode:
    • Reduction occurs at the cathode.
    • It acts as a positive terminal.
  • At Anode:
    • Oxidation occurs at the anode.
    • It acts as a negative terminal.
  • Example of electrolysis:
    • At Cathode:
      • Cu2+ + 2e- → Cu(s)   [E= 0.34V]
      • H+(aq) + e→ 1/2 H2(g)   [E0 = 0.00V]
    • It is a reduction reaction.
    •  At Anode:
      • Cl- → 1/2 Cl2(g) + e-1   [E0 = +1.36V]
      • 2H2O → O2 + 4H+(aq) + e-1  [E0 = +1.23V]
    • It is oxidation reaction.

 

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