Question
Download Solution PDFWhat type of defect causes F-centers in a crystal?
This question was previously asked in
ESE Electrical 2017 Official Paper
Answer (Detailed Solution Below)
Option 2 : Metal excess defect due to anion vacancies
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ST 1: UPSC ESE (IES) Civil - Building Materials
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Detailed Solution
Download Solution PDF- A point in a crystalline compound at which a negative ion missing from the crystal lattice has been replaced by an electron is called F-centres defect.
- Metal excess defect due to anionic vacancies causes F-centres in a crystal.
- This type of defect is observed in those crystals which are likely to form schottky defects.
- Alkali metal halides like NaCl and KCl show this type of defect.
- F-centre has been identified by electron spin resonance as an electron bound at a negative iron vacancy.
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