What type of defect causes F-centers in a crystal?

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ESE Electrical 2017 Official Paper
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  1. Stoichiometric defect
  2. Metal excess defect due to anion vacancies
  3. Metal excess defect due to extra cations
  4. Frenkel defect

Answer (Detailed Solution Below)

Option 2 : Metal excess defect due to anion vacancies
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  • A point in a crystalline compound at which a negative ion missing from the crystal lattice has been replaced by an electron is called F-centres defect.
  • Metal excess defect due to anionic vacancies causes F-centres in a crystal.
  • This type of defect is observed in those crystals which are likely to form schottky defects.
  • Alkali metal halides like NaCl and KCl show this type of defect.
  • F-centre has been identified by electron spin resonance as an electron bound at a negative iron vacancy.
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