The ratio of the longest wavelength to the shortest wavelength  in Paschen series of hydrogen spectrum is:

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Concept:

Hydrogen spectrum:

  • The hydrogen spectrum is an important piece of evidence to show the quantized electronic structure of an atom.
  • The hydrogen atoms of the molecule dissociate as soon as an electric discharge is passed through a gaseous hydrogen molecule.
  • It results in the emission of electromagnetic radiation initiated by the energetically excited hydrogen atoms.
  • The hydrogen emission spectrum comprises radiation of discrete frequencies.

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  • First three spectral series in the hydrogen spectrum: Lyman, Balmer, and Paschen series
  • The formula for the wavelength,  where, p =  higher energy level, n = lowest energy level, λ = wavelength
  • Here R = 109677 is called the Rydberg constant for the hydrogen atom

Calculation:

The longest wavelength in the Paschen series was obtained when p = 3, n = 4

For the longest wavelength, 

The shortest wavelength in the Paschen series was obtained when p = 3, n = ∞ 

For the shortest wavelength, 

Ratio, 

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