The major product formed in the following reaction is
F3 Vinanti Teaching 29.05.23 D125

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CSIR-UGC (NET) Chemical Science: Held on (15 Dec 2019)
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  1. F3 Vinanti Teaching 29.05.23 D126
  2. F3 Vinanti Teaching 29.05.23 D127
  3. F3 Vinanti Teaching 29.05.23 D128
  4. F3 Vinanti Teaching 29.05.23 D129

Answer (Detailed Solution Below)

Option 4 : F3 Vinanti Teaching 29.05.23 D129
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Detailed Solution

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Concept: 

The mechanism of the reaction follows Norrish Type-I and Type-II reaction.

Norrish Type-I reaction involves photochemical cleavage of \(\alpha,\beta\)-unsaturated ketone/aldehyde group where as Norrish Type-II proceeds via photochemical abstraction of \(\gamma\)-hydrogen.

Example:

Norrish Type-I:
F3 Vinanti Teaching 29.05.23 D132

Norrish Type-II
F3 Vinanti Teaching 29.05.23 D133
Explanation:

In this reaction photolysis of C-O bond occurs followed by removal of \(\gamma\)-hydrogen and then cyclisation.
F3 Vinanti Teaching 29.05.23 D134
Conclusion:

Therefore the correct option is option (4).

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