IUPAC name of neopentyl chloride is

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CUET Chemistry 10th Aug 2022 Official Paper
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  1. 1 - Chloro - 2, 2 - dimethylpropane
  2. 2 - Chloro - 1, 2 - dimethylpropane
  3. 2 - Chloro - 2 - Methylbutane
  4. 2 - Chloro - 2 - Methylpentane

Answer (Detailed Solution Below)

Option 1 : 1 - Chloro - 2, 2 - dimethylpropane
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Explanation:

The neopentyl group has four carbons, and all the carbons are bonded to a hydrogen atom except for one, which is bonded to a chlorine atom. The neopentyl group is attached to a propane chain, which has three carbons.

To name this compound using IUPAC nomenclature, we follow the following steps:

Identify the longest carbon chain: In this case, it is a propane chain with three carbons.

Number the carbon chain: We start numbering from the end nearest to the substituent, which is the neopentyl group. The carbon atom in the neopentyl group that is attached to the chlorine atom is assigned the lowest possible number. Therefore, it is numbered as carbon 1.

Identify and name the substituents: The neopentyl group is a substituent in this compound. The substituent name is derived from the name of the parent hydrocarbon, neopentane. The neopentyl group has four carbon atoms, so its prefix is "neo-".

Assign locants to the substituents: The substituent is attached to carbon 2 of the propane chain. Therefore, it is named as 2-neopentyl.

Name the functional group: The functional group in this compound is a halogen (chlorine) and is named as chloro.

Complete the name: Putting it all together, we get the IUPAC name of neopentyl chloride as 1-chloro-2,2-dimethylpropane.

1-chloro-2, 2-dimethylpropane
F4 Vinanti Teaching 10.05.23 D32

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