Ellingham diagram represents:

  1. change of ΔGº with temperature
  2. change of ΔHº with temperature.
  3. change of ΔGº with pressure
  4. change of (ΔGº – TΔSº) with temperature.

Answer (Detailed Solution Below)

Option 1 : change of ΔGº with temperature
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Explanation:

An Ellingham diagram is a graph showing the temperature dependence of the stability for compounds. This analysis is usually used to evaluate the ease of reduction of metal oxides and sulfides.

From the Ellingham diagram, we can say that any oxide with the lower value of ΔG° is more stable than oxide with a higher value of ΔG°. We can also predict that the oxide placed higher in the diagram can be reduced by the element involved in the formation of its oxide placed lower at that temperature in the diagram.

We know that, ΔGis Gibbs free energy. ΔG° is standard Gibbs energy change.

It is happening in case of ZnO for its reduction by Al at 1400℃.

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