Classify the following pollutants as primary pollutants (PP) and secondary pollutants (SP).

Ozone, Carbon monoxide, Particulate matter, Photochemical smog, Nitrogen oxides, Aerosol/mist, Hydrocarbons, Peroxy-Acetyl-Nitrate, Sulphur dioxide

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  1. PP: Ozone, Photochemical smog, Aerosol/mist, Peroxy-Acetyl-Nitrate

    SP: Carbon monoxide, Particular matter, Nitrogen oxides, Hydrocarbons, Sulphur dioxide

  2. PP: Ozone, Photochemical smog, Carbon monoxide, Particular matter, Nitrogen oxides

    SP: Aerosol/mist, Peroxy-Acetyl-Nitrate, Hydrocarbons, Sulphur dioxide

  3. PP: Carbon monoxide, Particulate matter, Nitrogen oxides, Hydrocarbons, Sulphur dioxide

    SP: Ozone, Photochemical smog, Aerosol/mist, Peroxy-Acetyl-Nitrate

  4. PP: Carbon monoxide, Particulate matter, Aerosol/mist, Peroxy-Acetyl-Nitrate

    SP: Nitrogen oxides, Hydrocarbons, Sulphur dioxide, Ozone, Photochemical smog

Answer (Detailed Solution Below)

Option 3 :

PP: Carbon monoxide, Particulate matter, Nitrogen oxides, Hydrocarbons, Sulphur dioxide

SP: Ozone, Photochemical smog, Aerosol/mist, Peroxy-Acetyl-Nitrate

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Detailed Solution

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Concept:

Air pollutants:

Pollutants are classified in different ways. According to origin pollutants are two types.

1). Primary pollutants:

  • These are directly emitted from the sources in the atmosphere in a harmful form.
  • They can be natural (volcanic eruptions or fires, for example) or of anthropogenic origin (carbon monoxide from vehicles).

2). Secondary Pollutants:

  • These are derived from primary pollutants due to chemical or photochemical reactions in the atmosphere they become hazardous after reaction in the air. 
  • The best known of the secondary pollutants is certain gases that are synthesized by photochemical reactions in the lower atmosphere.
  • The primary emitted chemicals in these reactions are hydrocarbons and gaseous oxides of nitrogen such as nitric oxide and nitrogen dioxide. 
  • Its origin lies in the interactions between the primary emissions in the atmosphere.

Examples of primary and secondary air pollutants:

Primary Pollutants

Secondary Pollutants

Carbon monoxide (CO)

Oxides of nitrogen (NOx, NO)

Sulfur oxides (SOx)

Hydrocarbons

Particulate matter (dust, ash, salt particles)

Ozone

Peroxy Acetyl – nitrate (PAN)

Photochemical smog

Formaldehyde

Sulphuric Acid

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